Organic Electrode Materials for Energy Storage and Conversion: Mechanism
ConspectusLithium ion batteries (LIBs) with inorganic intercalation compounds as electrode active materials have become an indispensable part of human life. However, the rapid increase in their annual production raises concerns about limited mineral reserves and related environmental issues. Therefore, organic electrode materials
Proton-Coupled Electron Transfer: The Engine of Energy Conversion and Storage
ACCESS. ABSTRACT: Proton-coupled electron transfer (PCET) underpins energy conversion in chemistry and biology. Four energy systems are described whose discoveries are based on PCET: the water splitting chemistry of the Artificial Leaf, the carbon xation fi chemistry of the Bionic Leaf-C, the nitrogen xation chemistry of the Bionic Leaf-N and
Discovery of a three-proton insertion mechanism in α-molybdenum trioxide leading to enhanced charge storage
This work provides new insights into the electrochemistry of proton intercalation in α-MoO 3 and demonstrates its promising future for high-power and large-scale energy storage applications
Highly Conductive Proton Selectivity Membrane Enabled by Hollow Carbon Sieving Nanospheres for Energy Storage
Ion conductive membranes (ICMs) with highly conductive proton selectivity are of significant importance and greatly desired for energy storage devices. However, it is extremely challenging to construct fast proton-selective
An Emerging Chemistry Revives Proton Batteries
All these features make it promising to develop novel energy storage based on proton electrochemistry. Here, we define the energy storage systems as "proton batteries",
Proton Batteries Shape the Next Energy Storage
A Novel Layered WO3 Derived from An Ion Etching Engineering for Ultrafast Proton Storage in Frozen Electrolyte. Aqueous proton batteries/pseudocapacitors are promising candidates for next‐generation electrochemical energy storage. However, their development is impeded by the lack of suitable electrode.
Structure evolution and energy storage mechanism of
Furthermore, the energy storage mechanism in this nano-crystalline spinel is interpreted as the co-intercalation of zinc ions and protons with some water. This work provides a new viewpoint of the structure evolution and correlated energy storage mechanism in spinel-type host materials, which would benefit the design and development of next-generation
Engineering Low-Cost Organic Cathode for Aqueous Rechargeable Battery and Demonstrating the Proton Intercalation Mechanism for Pyrazine Energy
Seeking organic cathode materials with low cost and long cycle life that can be employed for large-scale energy storage remains a significant challenge. This work has synthesized an organic compound, triphenazino[2,3-b](1,4,5,8,9,12-hexaazatriphenylene) (TPHATP), with as high as 87.16% yield. This c
Insights on the proton mechanism in carbonyl-based organic
Implementing proton insertion/removal in an aqueous battery has advantages like high safety, high rate, and low-temperature properties. The proton energy storage materials are mainly based on inorganic material in a strong acid electrolyte.Proton batteries attract much attention under neutral condition, especially based on the metal
β-MnO2 with proton conversion mechanism in rechargeable zinc
Facile synthesis and the exploration of the zinc storage mechanism of β-MnO2 nanorods with exposed (101) planes as a novel cathode material for high performance eco-friendly zinc-ion batteries. Aqueous Zn-ion batteries (ZIBs) have emerged as promising and eco-friendly next-generation energy storage systems to substitute lithium-ion batteries.
Aqueous Organic Batteries Using the Proton as a Charge Carrier
Proton as a charge carrier inherits the advantages of aqueous batteries such as the merits of rich reserves, low cost, and rapid kinetics of electrochemical storage. Meanwhile, finding suitable electrode materials is crucial for the development of APBs. Figure 1 shows the timeline of APBs, demonstrating the milestones of organic molecules
Protic ionic liquids in energy storage devices: past, present and future perspective
Electrochemical energy storage devices such as lithium-ion batteries (LIBs) and supercapacitors (SCs) have become essential in our society during the last decades. Nowadays these devices are used in a multitude of different applications, and their massive introduction in electric vehicles and stationary applications will further strengthen their
Insights into host materials for aqueous proton batteries: structure, mechanism and prospect
Rechargeable energy storage devices have been widely applied to meet the development of social green economy storage. Aqueous proton batteries (APBs) are regarded as one of the most promising energy storage devices for the next-generation batteries, benefiting from its reliable safety and reasonable profitability.
Proton-selective coating enables fast-kinetics high-mass-loading
Here, we discover that an ultrathin two-dimensional polyimine membrane, featured by dual ion-transport nanochannels and rich proton-conduction groups, facilitates rapid and selective proton
Proton storage chemistry in aqueous zinc‐organic
We also focus on the electrochemical mechanisms of proton storage in aqueous ZIBs. Three types of charge-storage reactions are summarized, including pure Zn 2+ intercalation, pure H + storage,
Electrochemical Proton Storage: From Fundamental
Finally, this review provides a framework for research directions of charge storage mechanism, basic principles of material structure design, construction
Energy & Environmental Science
Fig. 1 (a) Hopping Grotthuss mechanism for proton conductivity. (b) Newton''s cradle illustration of proton hopping Grotthuss mechanism in NiMn 3O 7 lattice. (c) Illustration of hydrated proton hopping via Grotthuss mechanism. Paper Energy & Environmental
Diffusion-free Grotthuss topochemistry for high-rate and long-life
These comparative studies highlight the correlation between the Grotthuss mechanism and high rate capability of proton storage in CuFe-TBA.
Insights into host materials for aqueous proton batteries: structure, mechanism
DOI: 10.1016/J.NANOEN.2021.106400 Corpus ID: 238675601 Insights into host materials for aqueous proton batteries: structure, mechanism and prospect @article{Li2021InsightsIH, title={Insights into host materials for aqueous proton batteries: structure, mechanism and prospect}, author={Jing Li and Hui-Huan Yan and Chiwei Xu
Discovery of fast and stable proton storage in bulk hexagonal
The discovery of unconventional materials and mechanisms that enable proton storage of micrometer-sized particles in seconds boosts the development of fast
Electrochemical Proton Storage: From Fundamental
Research progresses and strategies to promote the development of electrochemical proton storage based on various charge storage mechanisms, electrode materials, and
In-situ regulated competitive proton intercalation and
As shown in Fig. 1, a traditional Zn//MnO 2 battery shows a working voltage of 0.8-1.8 V vs. Zn 2+ /Zn, with an energy storage mechanism of the one-electron redox process of ion insertion/extraction [36], [37], [38].During the discharge process, proton and zinc ions
Micron-sized H2MoO3/PANI for superfast proton batteries in frozen electrolyte through Grotthuss mechanism
To evaluate the proton storage performance of the obtained H 2 MoO 3 /PANI, the electrochemical properties of the H 2 MoO 3 /PANI electrode were first tested in a three-electrode configuration in a voltage window of −0.60 to 0.35 V. Fig. S7 (online) shows the cyclic voltammetry (CV) curve in the initial cycle, in which the broad cathodic peaks at
Proton Batteries Shape the Next Energy Storage | Request PDF
Request PDF | On Jul 1, 2023, Chengxiang Huang and others published Proton Batteries Shape the Next Energy Storage | Find, read and cite all the research you need on ResearchGate In aqueous
Engineering Low‐Cost Organic Cathode for Aqueous Rechargeable Battery and Demonstrating the Proton Intercalation Mechanism for Pyrazine Energy
Seeking organic cathode materials with low cost and long cycle life that can be employed for large-scale energy storage remains a significant challenge. This work has synthesized an organic compound, triphenazino[2,3-b](1,4,5,8,9,12-hexaazatriphenylene) (TPHATP), with as high as 87.16% yield.
Proton Storage in Metallic H1.75MoO3 Nanobelts
Proton Storage in Metallic H 1.75 MoO 3 Nanobelts through the Grotthuss Mechanism Wangwang Xu College of Materials and Chemical Engineering, Hubei Provincial Collaborative Innovation Center for New Energy
Insights on the proton mechanism in carbonyl-based organic
Herein, we firstly uncover the special energy storage mechanism of carbonyl materials as proton acceptor in neutral electrolyte. Carbonyl groups adsorb water molecular and induce proton insertion, this diffusion-free mechanism determines its fast reaction kinetics, which helps to improve the power density.
Regulating proton distribution by ion exchange resin to achieve
Mild-acid Zn-MnO 2 batteries have emerged as a promising alternative to replace Li-ion batteries in large-scale energy storage systems, primarily due to their high safety and low cost. While there have been significant improvements in the electrochemical performance of Zn-MnO 2 batteries, the reaction mechanism of the MnO 2 cathode is
Proton-Coupled Electron Transfer: The Engine of Energy Conversion and Storage
Proton-coupled electron transfer (PCET) underpins energy conversion in chemistry and biology. Four energy systems are described whose discoveries are based on PCET: the water splitting chemistry of the Artificial Leaf, the carbon fixation chemistry of the Bionic Leaf-C, the nitrogen fixation chemistry of the Bionic Leaf-N and the Coordination
Unravelling the proton hysteresis mechanism in vacancy
To further reveal the proton hysteresis mechanism in V 2 O 3-x-CC, dynamic evolution process of H + with voltage in real-time was plotted in Fig. 5 c. The sharp decrease of pH during the first charge from near 1.12 V to 1.6 V may be related to the electrolysis of water ( Fig. 2 b) and the side reactions during activation process.
Discovery of a three-proton insertion mechanism in α-molybdenum trioxide leading to enhanced charge storage
Following this initial cycle, the MoO 3 electrode displayed a reversible discharge capacity of 362 mAh g −1, signifying a 72% improvement in capacity and 230% improvement in specific energy density compared to the two-proton mechanism (Fig. 2a 7) 35.
Search for a Grotthuss mechanism through the observation of proton
It is commonly accepted that there are two major mechanisms of proton transport 1,2,3,4,5,6,7: (1) the vehicular mechanism, where a proton moves via a molecular entity (i.e., a vehicle); and (2
Proton-selective coating enables fast-kinetics high-mass-loading
Sluggish Zn2+-dominated Faradic reactions lead to suboptimal charge-storage capacity and durability of aqueous zinc battery cathodes. Here, the authors present a proton-selective interfacial
Advanced aqueous proton batteries: working mechanism, key
Liu et al. proposed a β-MnO 2 energy storage mechanism for proton conversion. [114] It can be seen from figure 8 (a) that the characteristic peak intensity of
Electrochemical Proton Storage: From Fundamental
Research progresses and strategies to promote the development of electrochemical proton storage based on various charge storage mechanisms, electrode materials, and devices are discussed and summarized. Challenges and perspectives of the next-generation electrochemical proton storage technology are discussed. e-ISSN 2150-5551 CN 31
Insights into host materials for aqueous proton batteries:
The energy storage mechanisms in APBs are classified into three categories: (1) hydrogen insertion/extraction reaction mechanism, (2) chemical
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