Ultra-high-voltage Ni-rich layered cathodes in practical Li metal batteries enabled by a sulfonamide-based electrolyte | Nature Energy
By increasing the charging voltage, a cell specific energy of >400 W h kg−1 is achievable with LiNi0.8Mn0.1Co0.1O2 in Li metal batteries. However, stable cycling of high-nickel
Ultra-high open-circuit voltage of tin perovskite solar cells via
As a result, the use of indene-C60 bisadduct brings unprecedentedly high voltage of 0.94 V, which is over 50% higher than that of 0.6 V for device based on [6,6]-phenyl-C61-butyric acid methyl ester.
Additive engineering for robust interphases to stabilize high-Ni
@article{osti_1872753, title = {Additive engineering for robust interphases to stabilize high-Ni layered structures at ultra-high voltage of 4.8 V}, author = {Tan, Sha and Shadike, Zulipiya and Li, Jizhou and Wang, Xuelong and Yang, Yang and Lin, Ruoqian and Cresce, Arthur and Hu, Jiangtao and Hunt, Adrian and Waluyo, Iradwikanari and Ma, Lu
Self‐Healing Polymer Electrolyte for Dendrite‐Free Li Metal
Benefitting from the high ionic conductivity, wide electrochemical window and good interfacial stability, the self-healing polymer electrolyte enables stable cycling of the LiNi 0.8 Mn 0.1 Co 0.1 O 2 (NMC811) cathode under 4.7 V, achieving a high specific capacity of ≈228.8 mAh g −1 and capacity retention of 80.4% over 500 cycles. The new
Transregional electricity transmission and carbon
1. Introduction. China accounts for about one-third of global carbon dioxide emissions and one-quarter of greenhouse gas emissions (Wang et al., 2020; Zhou et al., 2021).Undoubtedly, China plays a crucial role in promoting global net-zero emissions, and the development of clean energy and efficient energy conversion is key (Wei et al.,
High-entropy enhanced capacitive energy storage
Nature Materials - Electrostatic capacitors can enable ultrafast energy storage and release, but advances in energy density and efficiency need to be made.
Ultra-high energy density integrated polymer dielectric
A record high energy storage density of 50.2 J cm −3 with an outstanding charge–discharge efficiency of 80% is achieved at 1000 kV mm −1 in relaxor-like PVDF, which is ascribed to reversible polar nanostructures generated by the constraining effect originating from continuous folded boundaries in the multilayer structure during rolling
Towards enhanced sodium storage of hard carbon anodes
The optimal sample exhibits a low specific surface area of 2.96 m 2 g −1 and high proportion of pseudo-graphitic domains. The structural advantages of the hard carbon contribute to a high reversible sodium storage capacity of 369.8 mAh g −1 with an initial Coulombic efficiency (ICE) of 82.5% at 20 mA g −1.
Fluence Selected by Taiwan Power Company for its Largest
There are 29 ultra-high voltage substations in Taiwan managed by the state-owned Taiwan Power Company (Taipower), with a plan of building a total of 160 MW of energy storage at Taipower sites.
Organic–Inorganic Hybrid Cathode with Dual Energy‐Storage Mechanism for Ultrahigh
Yet, the classical high-capacity materials (e.g., vanadium-based materials) provide a low discharge voltage, while organic cathodes with high operating voltage generally suffer from a low capacity. In this work, organic (ethylenediamine)–inorganic (vanadium oxide) hybrid cathodes, that is, EDA-VO, with a dual energy-storage mechanism, are designed for
Nonflammable quasi-solid electrolyte for energy-dense and long-cycling lithium metal batteries with high-voltage
In this work, we demonstrate a rigid-flexible coupling quasi-solid electrolyte for LMBs paired with the ultra-high-voltage NCM811 cathode, Energy Storage Mater., 39 (2021), pp. 186-193 View PDF View article View
Bipolar stackings high voltage and high cell level energy density
The resulting cells were expected to deliver a high output voltage and cell-level high energy densities through bipolar stacking. Download : Download high-res image (1MB) Download : Download full-size image; Energy Storage Mater., 45 (2022), pp. 969-1001. View PDF View article View in Scopus Google Scholar [4]
Ultra-high energy density integrated polymer dielectric
Flexible dielectric polymers with high energy storage density are needed for film capacitor applications including hybrid electric vehicles and medical apparatuses. Poly(vinylidene fluoride) (PVDF) is regarded as a promising candidate owing to its intrinsic high polarisation, outstanding processability, good mechanical properties, and high dielectric breakdown
Monolithic integrated micro-supercapacitors with ultra-high
INTRODUCTION. For truly realizing the Internet of Things consisting of miniaturized electronics, microscale electrochemical energy-storage systems with high systemic performance, superior cell-number density, tunable capacitance and output voltage are required [] this regard, on-chip interdigitated micro-supercapacitors
Ultrahigh Energy Storage Density in Glassy Ferroelectric Thin Films
Here, a strategy is proposed for enhancing recoverable energy storage density (W r) while maintaining a high energy storage efficiency (η) in glassy
China''s Growing Network Of Ultra-High Voltage Power Lines Has
Expensive and difficult to build, UHV lines transmit energy at 800,000 volts and above, double the voltage of conventional high-voltage lines, allowing them to transmit up to five times more
Ultra-high-voltage Ni-rich layered cathodes in practical Li metal
Here the authors design a sulfonamide-based electrolyte to enable a Li metal battery with a state-of-the-art cathode at an ultra-high voltage of 4.7 V while
High areal capacity, long cycle life 4 V ceramic all-solid-state Li
All-solid-state Li batteries (ASSBs) employing inorganic solid electrolytes offer improved safety and are exciting candidates for next-generation energy storage. Herein, we report a family of
Design of High-Voltage Stable Hybrid Electrolyte with an Ultrahigh
Abstract. Considering the high energy consumption during processing, and the low compliance and adhesion of ceramic electrolytes, the integration of polymer
High areal capacity, long cycle life 4 V ceramic all-solid-state Li
All-solid-state Li batteries (ASSBs) employing inorganic solid electrolytes offer improved safety and are exciting candidates for next-generation energy storage.
Transregional electricity transmission and carbon
Ultra-high voltage (UHV) transmission projects provide an effective way to alleviate the reverse distribution of energy in China, but do they reduce regional carbon emissions? Li et al., 2022). However, the unbalanced distribution of energy resources and energy demand between countries and regions, the distance between energy bases
Low-solvation electrolytes for high-voltage sodium-ion batteries | Nature Energy
Therefore, developing advanced functional electrolytes that enable minimum SEI dissolution and excellent compatibility with high-voltage cathodes is critical for the further development of stable
Optimal configuration of energy storage for remotely delivering
Xiao et al. (2020) evaluated the role of energy storage technology for remotely delivering wind power by ultra-high voltage lines. Wei et al. (2018) revealed the energy cost and CO2 emissions of UHV transformer substation in China based on an input-output analysis.
High-entropy enhanced capacitive energy storage
Here, we report a high-entropy stabilized Bi2Ti2O7-based dielectric film that exhibits an energy density as high as 182 J cm−3 with an efficiency of 78% at an electric field of 6.35 MV cm−1.
Solid polymer electrolyte with in-situ generated fast Li
Solid polymer electrolytes (SPEs) with profound compatibility for high-voltage cathodes and reliable operation over a board temperature range are in urgent
Hitachi Energy showcases the world''s first eco-efficient 420
Hitachi Energy today unveiled the world''s first eco-efficient 420-kilovolt (kV) circuit-breaker 1 in conjunction with CIGRE Session 2022.This breakthrough technology marks a significant milestone in its accelerated EconiQ™ high-voltage portfolio roadmap that was announced at CIGRE Session 2021.. For over two decades, the company has been investing in eco
A strongly complexed solid polymer electrolyte
A solid-state electrolyte with a wide electrochemical window, high Li-ion conductivity, and anti-dendritic growth properties are required for high-energy-density solid-state batteries. Here, we reported
A comprehensive review of supercapacitors: Properties, electrodes
The ionic conductivity of the best hydrogel electrolyte obtained by them is 81.27 mS/cm, which makes the carbon-based supercapacitors stable at 2 voltage window. This work provides a general strategy for the development of hydrogel polymer electrolytes with high voltage windows in flexible energy storage devices. 5.
Topology crafting of polyvinylidene difluoride electrolyte creates
Here, we propose an innovative method to accurately operate the molecular structure of PVDF and uniformly graft the phosphorus derivatives on its chains to
Ultra-stable and deeply rechargeable zinc metal anode enabled
1. Introduction. Recently, Metallic zinc (Zn) has attracted renewed attention and been regarded as a promising anode material for rechargeable aqueous electrochemical energy storage systems owing to its high theoretical specific capacity (5855 mAh cm −3 and 820 mAh g −1), cost-effectiveness, and inherent safety [1], [2], [3], [4].However, Zn
Organic–Inorganic Hybrid Cathode with Dual Energy‐Storage
In this work, organic (ethylenediamine)–inorganic (vanadium oxide) hybrid cathodes, that is, EDA-VO, with a dual energy-storage mechanism, are designed for ultrahigh-rate and
Achieving Ultra‐High Voltage (≈10 kV) Triboelectric
To further simplify the TENG-based HV power source system, a single electrode mode TENG (SE-TENG) with simple wiring is first employed to generate ultra-high voltage power in this work. By optimizing surface charge density and the thickness of packing layer between the primary electrode and reference electrode, a record value of
Monolithic integrated micro-supercapacitors with ultra-high systemic volumetric performance and areal output voltage
In addition, the M-MSC offered an ultra-high power density of 2204 W cm −3 (energy density of 0.7 mWh cm −3) in PVA/H 2 SO 4 and 825 W cm −3 (energy density of 6.2 mWh cm −3) in PVDF-HFP-EMIMBF 4, which is higher than that of a conventional 1 –10 3
Design of High-Voltage Stable Hybrid Electrolyte with an Ultrahigh
Considering the high energy consumption during processing, and the low compliance and adhesion of ceramic electrolytes, the integration of polymer into ceramic electrolytes provides a way to mitigate the interfacial issues. However, the severe ion concentration gradient, low ionic conductivity, and instability toward Li metal and high
Advances in high-voltage supercapacitors for energy storage
To achieve a zero-carbon-emission society, it is essential to increase the use of clean and renewable energy. Yet, renewable energy resources present constraints in terms of geographical locations and limited time intervals for energy generation. Therefore, there is a surging demand for developing high-perfo
Control design approach for improved voltage stability in
The ultra-capacitor having high energy density is able to give the high current or absorb it as per the requirement of the system. The simulation results for this case is shown below. The bus voltage is as usual at the rated 48 V and the moment load is varied in the system, we can see the changes in Figs. 11, 12 and 13 .
Ternary-phase layered cathodes toward ultra-stable and high
With the shortage of lithium resources, sodium-ion batteries (SIBs) are considered one of the most promising candidates for lithium-ion batteries. P2-type and O3-type layered oxides are one of the few cathodes that can access high energy density. However, they usually exhibit structural change, capacity decay, and slow Na ion kinetic.
A strongly complexed solid polymer electrolyte enables a stable
A solid-state electrolyte with a wide electrochemical window, high Li-ion conductivity, and anti-dendritic growth properties are required for high-energy-density solid-state batteries. Here, we reported a polyglycol oxide-based solid electrolyte constructed by incorporating a deep eutectic solvent within a d
Conformal PEDOT Coating Enables Ultra-High-Voltage and High
Single-crystal Ni-rich Li[NixMnyCo1–x–y]O2 (SC-NMC) cathodes represent a promising approach to mitigate the cracking issue of conventional polycrystalline cathodes. However, many reported SC-NMC cathodes still suffer from unsatisfactory cycling stability, particularly under high charge cutoff voltage and/or elevated temperature. Herein, we
Advances in high-voltage supercapacitors for energy storage
1. Introduction Recently, the concept of an RE100 society has become an important initiative around the globe, due to the significant effect of global warming and climate change, and it aims to supply 100% of the electricity required for the industry with renewable energy (RE). 1 However, diverse sources of renewable energy such as wind,
Ultra-thin and high-voltage-stable Bi-phasic solid polymer electrolytes for high-energy
Download : Download high-res image (200KB)Download : Download full-size imageDue to the phase separation phenomenon and interfacial Li-ion conduction, the bi-phase SSE exhibits a high ionic conductivity at room temperature. Coupling with LiNi 0.8 Co 0.1 Mn 0.1 O 2 (NCM 811) cathode and ultra-thin Li metal, the cell demonstrates
A tough Janus-faced CEI film for high voltage layered oxide
However, most CEI design strategies only focus on the electrochemical stability of the film. Herein a novel tough Janus-faced CEI film with excellent high-voltage stability and ultrahigh Young''s modulus ∼ 30 Gpa is in-situ constructed by succinonitrile (SN) and cyclohexylbenzene (CHB) additives. SN is adsorbed on electrode particles due
Implications of intercontinental renewable electricity trade for energy
Projects are under way for direct-current ultra-high-voltage transmission lines that would allow trading of renewable electricity across world regions. Guo et al. use integrated assessment models
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